Detection of muoniated organic free radicals in supercritical water
Digital Document
| Collection(s) |
Collection(s)
|
|---|---|
| Content type |
Content type
|
| Resource Type |
Resource Type
|
| Genre |
Genre
|
| Language |
Language
|
| Peer Review Status |
Peer Review Status
Peer Reviewed
|
| Persons |
Author (aut): Percival, Paul W.
Author (aut): Ghandi, Khashayar
Author (aut): Brodovitch, Jean-Claude
Author (aut): Addison-Jones, Brenda
Author (aut): McKenzie, Iain
|
|---|
| Origin Information |
|
|---|
| Abstract |
Abstract
Muoniated free radicals have been detected in muon-irradiated aqueous solutions at high temperatures and pressures. Results are presented for the cyclohexadienyl radical, formed by muonium addition to benzene, and for tert-butyl, formed by reaction of muonium with isobutene, itself formed in situ from the dehydration of the starting material, tert-butanol. This is the first report of the direct identification of organic free radicals in near critical and supercritical water.
|
|---|
| Publication Title |
Publication Title
|
|---|---|
| Publication Number |
Publication Number
Volume 2, Issue 20
|
| Publication Genre |
Publication Genre
|
| DOI |
DOI
10.1039/B005762M
|
|---|---|
| ISSN |
ISSN
1463-9076
|
| Identifier URI |
Identifier URI
|
|---|---|
| Use and Reproduction |
Use and Reproduction
© 2000. Royal Society of Chemistry.
|
| Rights Statement |
Rights Statement
|
| Related Item |
Related Item
|
|---|