Detection of an α-Muonium-substituted methyl radical

Brenda Addison-Jones; Paul W. Percival; Jean-Claude Brodovitch; Feng Ji; Dev Sharma; Stanislaw Wlodek

Summary

Collection(s)	Collection(s) DC Faculty Research & Scholarship
Content type	Content type Digital Document
Resource Type	Resource Type Text
Genre	Genre article
Language	Language English
Peer Review Status	Peer Review Status Peer Reviewed

Persons and Affiliations

Persons	Author (aut): Addison-Jones, Brenda Author (aut): Percival, Paul W. Author (aut): Brodovitch, Jean-Claude Author (aut): Ji, Feng Author (aut): Sharma, Dev Author (aut): Wlodek, Stanislaw

Origin Information

Date Created/Date Issued	1994
Publisher	Springer

Abstract/Description

Abstract

Reported here is the first observation of anα-Muonium-substituted methyl radical. The key to the success of this experiment was the use of a more stable precursor, trimethylsilyldiazomethane, in lieu of the prototypical diazomethane. The radical, CHMuSi(CH3)3 was observed by TF-μSR, with Aμ=187.6(2) MHz. This result is compared to literature values for the proton analogue and the isotope effect is discussed.

Publication/Container Information

Publication Title	Publication Title Hyperfine Interactions
Publication Number	Publication Number Volume 87

Identifiers

DOI	DOI 10.1007/BF02068473
ISSN	ISSN 0304-3843

Notes

Note

Note	publication status: Final article published

Access and Rights

Use and Reproduction	Use and Reproduction ©1994. Hyperfine Interactions. Springer.
Rights Statement	Rights Statement IN COPYRIGHT - EDUCATIONAL USE PERMITTED

Subjects and Classifications

Keywords	Keywords Stable Precursor Methyl Thin Film Isotope Effect Diazomethane

Relationships

Detection of an α-Muonium-substituted methyl radical

Cite this

Share