The effect of photocatalyst excited state lifetime on the rate of photoredox catalysis
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Peer Reviewed
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Author (aut): Ochola, Janet R.
Author (aut): Wolf, M. O.
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| Abstract |
Abstract
Four different iridium(III) polypyridyl complexes with varying excited state lifetimes are used as photocatalysts to study the effect of excited state lifetime on the rate of a prototypical photoredox-catalyzed reaction, the trifluoromethylation of quinoline. An improved mechanistic understanding of the photocatalysis is achieved, enabling guided optimization of reaction conditions and elucidating the role of the photocatalyst excited state lifetime on the rate of photocatalysis.
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Volume 14, Issue 38
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DOI
10.1039/C6OB01717G
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ISSN
1477-0520
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| Use and Reproduction |
Use and Reproduction
©2016. Royal Society of Chemistry.
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Rights Statement
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